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heat and mass transfer becomes large, and this is thought to be reasonable. Results for heat of pyrolysis and temperature for maximum decomposition rate are given in Tables 15.16 15.21. The heat of pyrolysis depends on the differences in the chemical structure of the material. The weight loss due to the volatiles released during the pyrolysis exhibits itself as an endotherm, which goes though a wellde ned minima. They correspond to the respective volatile loss that evolves from cellulose, polypropylene, or polystyrene. As for the temperature for maximum decomposition rate compare the results obtained with TGA with DSC results. The peak of the DSC curves evolves earlier than the peak from the TGA data. This may be due to the mass transfer limitations. The rate-controlling step (reaction
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HVL of the beam), the thickness of the tissue layer in the primary beam, and the entrance exposure. The amount of entrance exposure for a given film/screen combination will obviously be quite a bit higher to allow for absorption in the tissue thickness being imaged, and is a function of the same parameters, which can be represented as an absorption factor (AF). Values of AF are listed in Table 15-12 for combinations of tissue thickness and HVLs of x-ray beams and are accurate to 10% for source to skin distances of 45 90 cm. All other factors related to x-ray beam quality (e.g., kVp) are incorporated in the HVL determination; thus, the estimate of entrance skin exposure for the patient depends on an accurate determination of the HVL of the incident beam.
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